Answer: blackens

AnswerCrossword Clue
blackens(of the sky) Become dark as night or a storm approaches
blackensBLACKEN, to defame (to destroy the reputation of)
blackensBecome or make black or dark, esp. as a result of burning, decay, or bruising
blackensDye or color (the face or hair) black for camouflage or cosmetic effect
blackensDamage or destroy (someone's good reputation); defame